What size expansion vessel do I need?
Size it from the system water volume and pressures: minimum size = (0.04 × volume) ÷ (1 − Pi/Pf), using absolute pressures (gauge + 1). For a 100-litre system filled to 1 bar with a 2.5 bar maximum, that gives 4 L of expansion and a minimum vessel of about 9.3 litres — so you would fit the next standard size up.